Publications

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See some of our recent publications below.

2024

  1. N. Bashir, A. S. Leathard, M. McHugh, I. Hoffman, F. Shaon, J. A. Belgodere, A. F. Taylor, J. A. Pojman. On the use of modelling antagonistic enzymes to aid in temporal programming of pH and PVA-borate gelation. Mol. Syst. Des. Eng. 2024, advance article.
  2. B. R. Groce, A. V. Aucoin, Md A. Ullah, J. DiCesare, C. Wingfield, J. Sardin, J. T. Harris, J. C. Nguyen, P. Raley, S. S. Stanley, G. Palardy, J. A. Pojman. Free-Standing 3D Printing of Epoxy-Vinyl Ether Structures Using Radical-Induced Cationic Frontal Polymerization. ACS Appl. Polym. Mater. 2024 6(1), 572-582.

2023

  1. B. R. Groce, M. M. Ferguson, J. A. Pojman. Thermally initiated cationic frontal polymerization of epoxies and vinyl ethers through a lone onium salt. J. Polym. Sci. 2023 61(23), 3149-3158.
  2. B. R. Groce, E. E. Lane, D. P. Gary, D. T. Ngo, D. T. Ngo, F. Shaon, J. A. Belgodere, J. A. Pojman. Kinetic and Chemical Effects of Clays and Other Fillers in the Preparation of Epoxy–Vinyl Ether Composites Using Radical-Induced Cationic Frontal Polymerization.  ACS Applied Materials & Interfaces 2023 15(15), 19403-19413.
  3. B. A. Suslick, J. Hemmer, B. R. Groce, K. J. Stawiasz, P. H. Geubelle, G. Malucelli, A. Mariani, J. S. Moore, J. A. Pojman, N. R. Sottos. Frontal Polymerizations: From Chemical Perspectives to Macroscopic Properties and Applications. Chemical Reviews 2023 123(6), 3237-3298.
  4. D. P. Gary, D. Ngo, A. Bui, J. A. Belgodere, J. A. Pojman. Cure-on-demand ultra-high solid non-skid coatings through frontal polymerization. CoatingsTech 2023, Jan-Feb., 34-44.

2022

  1. Anowar H. Khan, Sophia P. Zhou, Margaret Moe, Braulio A. Ortega Quesada, Khashayar R. Bajgiran, Haley R. Lassiter, James A. Dorman, Elizabeth C. Martin, John A. Pojman, and Adam T. Melvin. Generation of 3D Spheroids Using a Thiol–Acrylate Hydrogel Scaffold to Study Endocrine Response in ER+ Breast Cancer. ACS Biomaterials Science 2022, 8, 3977-3985.
  2. Tiani, R., Pojman, J. A., Rongy, L. Critical Role of Layer Thickness in Frontal Polymerization. Journal of Physical Chemistry B 2022, 126, 3607-3618.
  3. Gary, D. P., Ngo, D., Bui, A., Pojman, J. A. Charge transfer complexes as dual thermal/photo initiators for free-radical frontal polymerization. J. Polym. Sci. 2022, 60(10), 1624-1630.
  4. Yuan Gao, Sarah Li, Jin-Young Kim, Imogen Hoffman, Sagar K. Vyas, John A. Pojman, and Philippe H. Geubelle. Anisotropic frontal polymerization in a model resin–copper composite. Chaos 2022, 32, 013109.

2021

  1. Yuan Gao, Fahima Shaon, Aditya Kumar, Samuel Bynum, Daniel Gary, David Sharp, John A. Pojman, and Philippe H. Geubelle. Rapid frontal polymerization achieved with thermally conductive metal strips. Chaos 2021, 31, 073113.
  2. Mai, A.Q., Bánsági, T., Taylor, A.F. Pojman, J. A. Reaction-diffusion hydrogels from urease enzyme particles for patterned coatings. Communications Chemistry 2021, 4, 101.
  3. Anowar H. Khan, Noah Mulherin Smith, Michael P. Tullier, B. Seth Roberts, Derek Englert, John A. Pojman, and Adam T. Melvin. Development of a Flow-free Gradient Generator Using a Self-Adhesive Thiol-acrylate Microfluidic Resin/Hydrogel (TAMR/H) Hybrid System. ACS Applied Materials & Interfaces 2021, 13 (23), 26735-26747.
  4. Groce, B. R.; Gary, D. P.; Cantrell, J. K.; Pojman, J. A. Front Velocity Dependence on Vinyl Ether and Initiator Concentration in Radical-Induced Cationic Frontal Polymerization of Epoxies. Journal of Polymer Science 2021, 59 (15), 1678-1685.
  5. Pojman, J. A., A New Approach to Manufacturing with Frontal Polymerization to Generate Patterned Materials. ACS Cent. Sci. 2021, 7, 534−535.

2020

  1. Upadhyay, J.;  Bounds, C. O.;  Totaro, N.;  Thakuri, S.;  Garber, L.;  Vincent, M.;  Huang, Z.; Pojman, J. A. Production and analysis of stable microfluidic devices with tunable surface hydrophilicity via the in-situ tertiary-amine catalyzed Michael addition of a multifunctional thiol to a multifunctional acrylate. European Polymer Journal 2020, 126, 109482. 
  2. Pojman, J. A., Cure-on Demand Materials Based on Frontal Polymerization. CSJ (Chem. Soc. Jpn.) Current Review 2020, 35, 163 -169.
  3. Mai, A. Q.;  Davies, J.;  Nguyen, D.;  Carranza, A.;  Vincent, M.; Pojman, J. A., Microparticles and latexes prepared via suspension polymerization of a biobased vegetable oil and renewable carboxylic acid. J. Appl .Polym. Sci 2020, 138, e50180.
  4. Khan, A. H.;  Cook, J. K.;  Wortmann III, W. J.;  Kersker, N. D.;  Rao, A.;  Pojman, J. A.; Melvin, A. T., Synthesis and characterization of thiol-acrylate hydrogels using a base-catalyzed Michael addition for 3D cell culture applications. J Biomed Mater Res. Part B: Applied Biomaterials 2020, 108B, 2294–2307.
  5. Gary, D. P.;  Bynum, S.;  Thompson, B. D.;  Groce, B. R.;  Sagona, A.;  Hoffman, I. M.;  Morejon-Garcia, C.;  Weber, C.; Pojman, J. A., Thermal transport and chemical effects of fillers on free-radical frontal polymerization. Journal of Polymer Science 2020, 58 (16), 2267-2277.
  6. Fazende, K. F.;  Gary, D. P.;  Mota-Morales, J. D.; Pojman, J. A., Kinetic Studies of Photopolymerization of Monomer-Containing Deep Eutectic Solvents. Macromol. Chem. Phys. 2020, 1900511.
  7. Bansal, K.;  Pojman, J. A.;  Webster, D.; Quadir, M., Frontal Polymerization of a Thin Film on a Wood Substrate. ACS Macro Letters 2020, 9, 169-173.

2019

  1. Yang, D.;  Fan, J.;  Cao, F.;  Deng, Z.;  Pojman, J. A.; Ji, L., Immobilization adjusted clock reaction in the urea–urease–H+ reaction system. RSC Advances 2019, 9 (7), 3514-3519.
  2. Pojman, J. A., Mathematical modeling of frontal polymerization. Mathematical Modelling of Natural Phenomena 2019, 14 (6), 604.
  3. Markovic, V. M.;  BánságiJr., T.;  McKenzie, D.;  Mai, A.;  Pojman, J. A.; Taylor, A. F., Influence of reaction-induced convection on quorum sensing in enzyme-loaded agarose beads. Chaos: An Interdisciplinary Journal of Nonlinear Science 2019, 29 (3), 033130.
  4. Hong, S.;  Sun, X.;  Lian, H.;  Pojman, J. A.; Mota-Morales, J. D., Zinc chloride/acetamide deep eutectic solvent-mediated fractionation of lignin produces high- and low-molecular-weight fillers for phenol-formaldehyde resins. Journal of Applied Polymer Science 2019, (0), 48385.
  5. Bynum, S.;  Tullier, M.;  Morejon-Garcia, C.;  Guidry, J.;  Runnoe, E.; Pojman, J. A., The effect of acrylate functionality on frontal polymerization velocity and temperature. Journal of Polymer Science Part A: Polymer Chemistry 2019, 57 (9), 982-988.
  6. Anoosha, F.;  Leah, G.;  Cong, C.;  Fariborz, T.;  Timothy, B. T.;  Ram, D.;  John, A. P.; Daniel, H., Fabrication and characterization of thiol-triacrylate polymer via Michael addition reaction for biomedical applications. Biomedical Materials 2019, 14 (1), 015001.

2018

  1. Stewart, S.;  Marin, D.;  Tullier, M.;  Pojman, J.;  Meiburg, E.; Bunton, P., Stabilization of Miscible Viscous Fingering by a Step Growth Polymerization Reaction. Experiments in Fluids 2018, 59, 114.
  2. Mota-Morales, J. D.;  Sánchez-Leija, R. J.;  Carranza, A.;  Pojman, J. A.;  del Monte, F.; Luna-Bárcenas, G., Free-radical polymerizations of and in deep eutectic solvents: Green synthesis of functional materials. Progress in Polymer Science 2018, 78, 139-153.

2017

  1. Viner, G.;  La Monica, T.;  Lombardo, R.; Pojman, J. A., Effect of pseudo-gravitational acceleration on the dissolution rate of miscible drops. Chaos 2017, 27, 104603.
  2. Tullier, M. P.; Pojman, J. A., Cure-on-Demand Acrylamide Grout Using Frontal Polymerization. J. Mater. Civ. Eng. 2017, 29 (10), 06017014.
  3. Fazende, K. F.;  Phachansitthi, M.;  Mota-Morales, J. D.; Pojman, J. A., Frontal Polymerization of Deep Eutectic Solvents Composed of Acrylic and Methacrylic Acids. J. Polym. Sci. A Polym. Chem. 2017, 55 (24), 4046-4050.
  4. Carranza, A.;  Romero-Perez, D.;  Almanza-Reyes, H.;  Bogdanchikova, N.;  Juarez-Moreno, K.;  Pojman, J. A.;  Velasquillo, C.; Mota-Morales, J. D., Nonaqueous Synthesis of Macroporous Nanocomposites Using High Internal Phase Emulsion Stabilized by Nanohydroxyapatite. Adv. Mater. Interfaces 2017, 1700094-n/a.
  5. Bunton, P. H.;  Tullier, M. P.;  Meiburg, E.; Pojman, J. A., The effect of a crosslinking chemical reaction on pattern formation in viscous fingering of miscible fluids in a Hele-Shaw cell. Chaos 2017, 27, 104614.