Publications

Mentored Graduate co-authors are underlined. (#) denotes mentored Undergraduate co-authors. (*) denotes Sviatoslav Baranets as the corresponding author.

Since at LSU

2024

52.     M. Ishtiyak, S.M.G.K. Samarakoon, T. Kandabadage Don, S.R. Watts, S. Baranets*. Novel Ternary Zintl Phosphide Halides Ba3P5X (X = Cl, Br) with 1D Helical Phosphorus Chains: Synthesis, Crystal and Electronic Structure. Nanoscale, (accepted), 2024, [DOI]

Graphical abstract for Ba3P5X paper

51.     S.M.G.K. Samarakoon, A. Ovchinnikov, S. Baranets*, S. Bobev. Ba5Sb8: The Highest Homologue of the Family of Binary Semiconducting Barium Antimonides BanSb2n–2 (n ≥ 2). Inorganics, 12(1), 2024, 3. [DOI]

Graphical abstract for Ba5Sb8 paper

2023

50.    S. Baranets*, A. Ovchinnikov, S.M.G.K. Samarakoon, S. Bobev. Synthesis, Crystal and Electronic Structure of the Zintl Phase Ba16Sb11. A case of uncovering greater structural complexity via monoclinic distortion of the tetragonal Ca16Sb11 structure type. Zeitschrift fur Anorganische und Allgemeine Chemie, 649 (18), 2023, e202300148. [DOI]
Cover of the journal issue

2022

49.    W. Peng, S. Baranets, S. Bobev. Synthesis, Crystal and Electronic Structure of the New Ternary Compound Ca3InAs3. Crystals, 12 (10), 2022, 1467. [DOI]

48.    M.O. Ogunbunmi, S. Baranets, S. Bobev. Enhanced thermoelectric performance in the Zintl antimonides (Ca,RE)9Cd4Sb9 (RE = Rare-Earth Metal). Synergy between increased structural complexity and drive towards optimized chemical bonding. Materials Today Advances, 16, 2022, 100310. [DOI]

47.     R. Janzen#S. Baranets, S. Bobev. Synthesis, structural characterization, and properties of the new Zintl phases Eu10Mn6Bi12 and Yb10Zn6Sb12Dalton Transactions, 51, 2022, 13470-13478 [DOI]

Prior to LSU

46.     W. Peng, S. Baranets, S. Bobev. Synthesis, crystal, and electronic structure of BaLixCd13–x (x ≈ 2). Frontiers in Chemistry, 2022, 10, 991625. [DOI]

45.    M.O. Ogunbunmi, S. Baranets, S. Bobev. Structural Complexity and Tuned Thermoelectric Properties of a Polymorph of the Zintl Phase Ca2CdSb2 with a Non-centrosymmetric Monoclinic Structure. Inorganic Chemistry, 61 (28), 2022, 10888-10897. [DOI]

44.    S. Baranets, A. Balvanz#, G.M. Darone, S. Bobev. On the Effects of Aliovalent Substitutions in Thermoelectric Zintl Pnictides. Varied Polyanionic Dimensionality and Complex Structural Transformations–The Case of Sr3ZnP3 vs Sr3AlxZn1–xP3. Chemistry of Materials, 34 (9), 2022, 4172-4185. [DOI]

43.    M.O. Ogubunmi, S. Baranets, S. Bobev. Materials design, synthesis, and transport properties of disordered rare-earth Zintl bismuthides with the anti-Th3P4 structure type. Dalton Transaction, 51, 2022, 5227-5238. [DOI]
 
42.    S. Baranets*, G.M. Darone, S. Bobev. Structural Diversity Among Multinary Pnictide Oxides. A Minireview Focused on Semiconducting and Superconducting Heteroanionic Materials. Zeitschrift für Kristallographie – Crystalline Materials, 237 (1-3), 2022, 1-26. [DOI]  

41.     J. Qu, A. Balvanz#, S. Baranets, S. Bobev, P. Gorai. Computational Design of Thermoelectric Alloys Through Optimization of Transport and Dopability. Materials Horizons, 9 (2), 2022, 720-730. [DOI]

2021

40.    J. Tian, V.N. Ivanovski, M. Abeykoon, R.M. Martin, S. Baranets, C. Martin, Y. Liu, Q. Du, A. Wang, S. Chen, X. Tong, W. Zhang, S. Bobev, V. Koteski, C. Petrovic. Absence of the long-range magnetic order in Fe1–δTe2 (δ ≈ 0.1) crystals. Physical Review B, 104, 2021, 224109. [DOI]

39.    S. Baranets, A. Ovchinnikov, S. Bobev, Structural diversity of the Zintl Pnictides with Rare-Earth Metals (Book chapter) // Handbook of Physics and Chemistry of Rare Earth Elements. Elsevier, 2021. V. 60, 227-324. [DOI]

38.    M.O. Ogubunmi, S. Baranets, S. Bobev. Synthesis and Transport Properties of the Family of Zintl Phases Ca3RESb3 (RE = La–Nd, Sm, Gd–Tm, Lu). Exploring the Roles of Crystallographic Disorder and Core 4f Electrons for Enhancing Thermoelectric Performance. Chemistry of Materials, 33 (23), 2021, 9382-9392. [DOI]

37.    S. Baranets, A. Ovchinnikov, S. Bobev. Synthesis, crystal and electronic structure of BaLi2Cd2Ge2. Zeitschrift für Naturforschung B, 76 (10-12), 2021, 689-697 [DOI]

36.    S.I. Orysyk, S. Baranets*, P. Borovyk, L. Palchykovska, Yu. Zborovskii, V. Orysyk, A. Likhanov, M. Platonov, D. Kovalskyy, T. Shyryna, Ye. Danylenko, V. Hurmach, V. Pekhnyo, M. Vovk. Mononuclear π-complexes of Pd(II) and Pt(II) with 1-allyl-3-(2-hydroxyethyl)thiourea: synthesis, structure, molecular docking, DNA binding ability, and genotoxic activity. Polyhedron, 210, 2021, 115477. [DOI]

35.    A. Balvanz#, S. Baranets, M. Ogunbunmi, S. Bobev. Two Polymorphs of BaZn2P2: Crystal Structures, Phase Transition, and Transport Properties. Inorganic Chemistry, 60 (18), 2021, 1426-1435. [DOI]

34.    S. Baranets, S. Bobev. Transport properties and thermal behavior of YbMnSb2 semimetal above room temperature. Journal of Solid State Chemistry, 303, 2021, 122467. [DOI]

33.    M.O. Ogunbunmi, S. Baranets, A. Childs, S. Bobev. The Zintl phases AIn2As2 (A = Ca, Sr, Ba): New topological insulators and thermoelectric material candidates. Dalton Transaction, 50, 2021, 9173-9184. [DOI]

32.    S. Baranets, A. Ovchinnikov, O. Dmitrenko, S. Bobev. Structural Uniqueness of the [Nb(As5)2]5– Cluster in the Zintl phase Cs5NbAs10. Journal of Physical Chemistry A, 125 (20), 2021, 4323-4333. [DOI]

31.     S. Baranets, A. Ovchinnikov, S. Bobev. Complex Structural Disorder in the Zintl Phases Yb10MnSb9 and Yb21Mn4Sb18. Inorganic Chemistry, 60 (9), 2021, 6702-6711. [DOI]

30.    J. Sinclair#, S. Baranets, S. Bobev. Synthesis and structural characterization of orthorhombic Cu3–δSb (δ ≈ 0.1) and hexagonal Cu3Sb1-xInx (x ≈ 0.2) phases. Zeitschrift für Kristallographie – Crystalline Materials, 236 (3-4), 2021, 61-70. [DOI]

29.    D.M. Smiadak, S. Baranets, M. Rylko, M. Marshall, M. Calderon-Cueva, S. Bobev, A. Zevalkink. Single crystal growth and characterization of new Zintl phase Ca9Zn3.1In0.9Sb9. Journal of Solid State Chemistry, 296, 2021, 121947. [DOI]

28.    S. Baranets, S. Bobev. Caught in Action. The Late Rare Earth Thulium and Lutetium Substituting Aluminum Atoms in the Structure of Ca14AlBi11. Journal of the American Chemical Society, 143 (1), 2021, 65-68. [DOI]

2020

27.    A. Balvanz#, J. Qu, S. Baranets, E. Ertekin, P. Gorai, S. Bobev. New n-type Zintl Phases for Thermoelectrics: Discovery, Structural Characterization and Band Engineering of the Compounds A2CdP2 (A = Sr, Ba, Eu). Chemistry of Materials, 32 (24), 2020, 10697-10707. [DOI] 

26.    K. Rajput, S. Baranets, S. Bobev. Observation of an unexpected n-type semiconducting behavior in the ternary Zintl phase Eu3InAs3, Chemistry of Materials, 32 (22), 2020, 9616-9626. [DOI]

25.    A. Balvanz#, S. Baranets, S. Bobev. Synthesis, Structural Characterization, and Electronic Structure of the Novel Zintl Phase Ba2ZnP2. Acta Crystallographica C, 76, 2020, 869-873. [DOI]

24.    A. Wang, S. Baranets, Y. Liu, X. Tong, E. Stavitski, J. Zhang, Y. Chai, W.-G. Yin, S. Bobev, C. Petrovic. Magnetic mixed valent semimetal EuZnSb2 with Dirac states in the band structure. Physical Review Research, 2, 2020, 033462. [DOI]

23.    S. Baranets, S. Bobev. Ca14AlBi11 – a new Zintl phase from earth-abundant elements with a great potential for thermoelectric energy conversion. Material Today Advances, 7, 2020, 100094. [DOI]

22.    G.M. Darone, S.A. Baranets*, S. Bobev. On the new oxyarsenides Eu5Zn2As5O and Eu5Cd2As5O. Crystals, 10 (6), 2020, 475. [DOI]

21.     A. Balvanz#, S. Baranets, S. Bobev. Synthesis and structural characterization of the new Zintl phases Ba3Cd2P4 and Ba2Cd2P3. Rare example of small gap semiconducting behavior with negative thermopower within the range 300 K – 700 K. Journal of Solid State Chemistry, 289, 2020, 121476. [DOI]

20.    S.A. Baranets*, A.B. Childs, H. He, S. Bobev. Complex disorder in type-I clathrates: Synthesis and structural characterization of A8GaxSn46–x (A = Rb, Cs; 6.9 < x < 7.5). Crystals, 10 (4), 2020, 298. [DOI]

2019

19.    S. Baranets, M. Schafer, S. Bobev. Synthesis and structural characterization of the type-I clathrates K8AlxSn46–x and Rb8AlxSn46–x (x ≈ 6.4–9.7). Acta Crystallographica C, 75, 2019, 1535-1540. [DOI]

18.    S. Baranets, G.M. Darone, S. Bobev. Synthesis and structure of Sr14Zn1+xAs11 and Eu14Zn1+xAs11 (x ≤ 0.5). New members of the family of pnictides isotypic with Ca14AlSb11, exhibiting a new type of structural disorder. Journal of Solid State Chemistry, 228, 2019, 120990. [DOI]

17.    A.B. Childs, S. Baranets, S. Bobev. Five new ternary indium-arsenides discovered. Synthesis and structural characterization of the Zintl phases Sr3In2As4, Ba3In2As4, Eu3In2As4, Sr5In2As6, and Eu5In2As6. Journal of Solid State Chemistry, 278, 2019, 120889. [DOI]

16.    S. Baranets, L. Voss, S. Stoyko, S. Bobev. Synthesis, Crystal Structure, and Physical Properties of the Solid Solutions Ca14–xRExCdSb11 (RE = La–Nd, Sm, Gd–Yb, x ≈ 0.85 ± 0.15). Journal of Applied Physics, 125, 2019, 245101. [DOI]

15.    S. Baranets, S. Bobev. From the Ternary Phase Ca14Zn1+δSb11 (δ ≈ 0.4) to the Quaternary Solid Solutions Ca14–xRExZnSb11 (RE = La–Nd, Sm, Gd, x ≈ 0.9). A Tale of Electron Doping via Rare-Earth Metal Substitutions and the Concomitant Structural Transformations. Inorganic Chemistry, 58, 2019, 8506-8516. [DOI]

2018

14.    S. Baranets*, G.R. Kosmambetova, L.B. Kharkova, P.E. Strizhak. Rhodium selenochlorides: Synthesis, properties, and application in heterogeneous catalysis (Book chapter) // Chemical elements (Fluorine, Rhodium, and Rubidium): Properties, Synthesis, and Applications. Nova Science Publishers Inc., 2018, 95-126. [ISBN]

13.    S. Baranets, H. He, S. Bobev. Niobium-bearing arsenides and germanides from elemental mixtures not involving niobium: a new twist to an old problem in solid-state synthesis. Acta Crystallographica C, 74, 2018, 623-627. [DOI]

12.    S.A. Baranets, O.G. Yanko, L.B. Kharkova, V.V. Subotin. Complex formation in Os-Chal-Hal systems (Chal – S, Se, Te; Hal – Cl, Br). Ukrainian Chemistry Journal, 84 (9), 2018, 10-21. [link]

2017

11.     V.V. Subotin, O.G. Yanko, P.Yu. Demchenko, L.B. Khar’kova, R.E. Gladyshevskii, S.A. Baranets. New trinuclear cluster rhenium selenosulfidobromide Re3Se3S4Br13: Synthesis, structure, catalytic properties. Ukrainian Chemistry Journal, 83 (9), 2017, 3-11. [link]

2016

10.    S.V. Volkov, L.B. Khar’kova, S.A. Baranets*, O.G. Yanko, P.E. Strizhak, G.R. Kosmambetova, V.I. Gritsenko. Catalytic properties of RhSe2/Ga/H-ZSM-5 system in the reaction of glycerol dehydration in the gas phase. Russian Journal of Applied Chemistry, 89(2), 2016, 233-237. [DOI]

2015

9.     Patent 102158 Ukraine, IPC C01G 55/00. 26.10.2015, Bul. № 20. The method of obtaining selenobromide of iridium Ir2Se9Cl6. S.V. Volkov, R.E. Gladyshevskii, L.B. Khar’kova, O.G. Yanko, P.Yu. Demchenko, S.O. Baranets, V.V. Subotin, Е.М. Mashkova, А.S. Nikolenko.

8.     S.A. Baranets, Yu.V. Mironov, A.I. Smolentsev, S.V. Volkov, L.B. Kharkova, O.G. Yanko. Structure of the Os2S2Br4(4-CNPy)4 complex. Journal of Structural Chemistry, 56(6), 2015, 1198-1200. [DOI]

7.     O.G. Yanko, L.B. Khar’kova, S.A. Baranets, Z.A. Fokina, N.G. Aleksandrova, E.M. Mashkova, V.V. Subbotin. Synthesis and structure of chalcohalides of platinum and rare metals. Ukrainian Chemistry Journal, 81(11), 2015, 61-68. [link]

2014

6.     S.V. Volkov, S.A. Baranets*, O.G. Yanko, L.B. Kharkova, P.Yu. Demchenko, R.Ye. Gladyshevskii. Structure of rhodium selenobromide Rh2Se9Br6. Ukrainian Chemistry Journal, 80(6), 2014, 85-86. [link]

5.     S.V. Volkov, S.A. Baranets, P.Yu. Demchenko, O.G. Yanko, Z.A. Fokina, L.B. Kharkova, R.Ye. Gladyshevskii, A.S. Nikolenko. Synthesis and structure of the first osmium thioselenobromide Os2Se5S7Br8. Ukrainian Chemistry Journal, 80(5), 2014, 24-28. [link]

2013

4.     Patent 85704 Ukraine, IPC C01G 55/00. 25.11.2013, Bul. № 22. The method of obtaining selenobromide of rhodium Rh2Se9Br6. S.V. Volkov, R.E. Gladyshevskii, O.G. Yanko, L.B. Khar’kova, P.Yu. Demchenko, S.O. Baranets, Е.М. Mashkova, А.S. Nikolenko.

3.     S.A. Baranets, Z.A. Fokina, P.Yu. Demchenko, O.G. Yanko, A.S. Nikolenko, L.B. Kharkova, R.E. Gladyshevskii, S.V. Volkov. Isostructural selenohalides of rhodium Rh2Se9Hal6 (Hal – Cl, Br). Ukrainian Chemistry Journal, 79 (9), 2013, 3-9. [link]

2.     S.A. Baranets, P.Yu. Demchenko, O.G. Yanko L.B. Kharkova, R.E. Gladyshevskii, A.S. Nikolenko, S.V. Volkov. Synthesis and structure of ruthenium selenobromide Ru2Se6Br12. Ukrainian Chemistry Journal, 79 (3), 2013, 7-10. [link]

2012

1.     S.V. Volkov, R.E. Gladyshevskii, Yu.V. Mironov, P.Yu. Demchenko, O.G. Yanko, A.I. Smolentsev, Z.A. Fokina, L.B. Khar’kova, S.A. Baranets. Osmium Thioselenochloride Os2S6Se2Cl6: Synthesis, Cluster Isolation, and Structure. Russian Journal of Coordination Chemistry, 38 (3), 2012, 167-172. [DOI]